Do you mean "A = 1", "B = 2" , etc, etc?
Assuming that, I don't know if there is a way to do it automatically, I would just write it out as an array.
<?php
$arr = array(
"A" => 1,
"B" => 2,
"C" => 3,
"D" => 4,
"E" => 5,
"F" => 6,
"G" => 7,
"H" => 8,
"I" => 9,
"J" => 10,
"K" => 11,
"L" => 12,
"M" => 13,
"N" => 14,
"O" => 15,
"P" => 16,
"Q" => 17,
"R" => 18,
"S" => 19,
"T" => 20,
"U" => 21,
"V" => 22,
"W" => 23,
"X" => 24,
"Y" => 25,
"Z" => 26);
echo $arr["Z"]; // Displays 26
echo $arr["M"]; // Displays 13
?>